Chlorine: Difference between revisions

'''Chlorine''' is the element that has the atomic number 17, and the symbol Cl. There is an abundance of chlorine in nature since it is found in common salt as one of the two elements making up sodium chloride. When chlorine is in the form of a gas, its color becomes greenish yellow, and its weight is more than twice that of air.  Chlorine gas has a suffocating odor and is very poisonous to every living thing. It is perhaps best known for its powerful disinfecting activity.[http://en.wikipedia.org/wiki/Chlorine]

Chlorine is usually found combined in nature because of its reactivity, as a gas each molecule has two atoms of chlorine. It is prepared commercially by passing electricity through a water solution of sodium chloride or through molten sodium chloride. Since sodium is very desirable for making washing soda, Chlorine was available in large quantities cheaply, and its chemistry was thoroughly explored. Chlorine gases are made up of diatomic molecules, as the formula Cl₂. The gas can be smelled in the air at 3 parts per million(ppm), and is irritating to the nose, mouth, and lungs. It causes throat irritation at 15 ppm, coughing at 30 ppm, and causes deadly effects after a few deep breaths at 1,000 ppm.

Chlorine gas is easy to dissolve in water, and chemical reactions occur that produce hydrochloric acid (HCl) and hypochlorous acid (HOCl), plus some unreacted Cl₂. This is called chlorine water and it is used to kill [[germs]] in water or to bleach papers and fabrics.   

Chlorinated hydrocarbons have had some of their hydrogen atoms replaced by chlorine atoms. A variety of chlorinated hydrocarbons have been used as [[insecticides]]. One of the earliest to be used was DDT, dichlorodiphenyl-trichloroethane. However, it caused serious environmental problems, and it is not used as much as before in the [[United States]].  

Other chlorinated hydrocarbons are used as pesticides in the farms, but all of these compounds are very stable so they last a long time in the environment, and are becoming a serious problem.[http://science.jrank.org/pages/1438/Chlorine-Properties-uses-chlorine.html]

Chlorine is abundant in the lithosphere, and it is estimated to be about 0.045%. Its strong chemical affinity for other elements means that it never occurs in the free state, except as a minor component of the gaseous output from volcanic eruptions. Chlorine is a compound of the most common minerals; rock salt or halite(NaCl), sylvite(KCl) and carnallite(MgCl12.KCl.6H20).

Chlorine salts liquefy in the hydrosphere (oceans, lakes and rivers) instead of being spread out in the lithosphere (rocks and minerals).  NaCl, sodium chloride, is the most common element of the alkali metals in the hydrosphere as well as in the lithosphere. Thus, it's named common salt. The average concentration in seawater is approximately 2,6%. Table salt plays an irreplaceable function in the human diet and the uneven distribution of its deposits over the earth's crust has played an important role in conditioning the pattern of civilization in time and space.

Chlorine was used during World War I as a choking (pulmonary) agent, an airborne poisonous weapon of mass destruction. Chlorine is one of the most commonly manufactured chemicals in the United States. It is used in the production of textile processing, petroleum products, medicines, antiseptics, insecticides, food, solvents, paints, plastics, and many other consumer products. Chlorine is also used in drinking water and swimming pool water to kill harmful bacteria. Household chlorine bleach can release chlorine gas if it is mixed with other cleaning agents. Chlorine is also as used as part of the sanitation process for industrial waste and sewage.

In 1774, '''Karl Wilhelm Scheele''' discovered Chlorine. Scheels thought that chlorine was an oxide of murium, or hydrochloric acid. Scheeles experimented by heating manganese dioxide and hydrochloric acid. From this experiment he discovered a greenish, yellow gas, which was chlorine. However, Scheeles did not consider chlorine as an element. In 1810, '''Humphrey Davy''' named chlorine and established it as an element. It was named after the Greek word chloros, which means pale green.

Chlorine was first introduced as a weapon during the World War I by the Germans on April 22, 1915. The chlorine weapons failed because they were not prepared well, but some chlorine poisons are more dangerous than others. It is alleged that Haber's role in the use of chlorine as a deadly weapon drove his wife, Clara Immerwahr, to suicide. After its first use, chlorine was utilized by both sides as a chemical weapon, but it was soon replaced by the more deadly gases phosgene and mustard gas.

Chlorine gas was also used in the Iraq War as a chemical weapon against the local population and coalition forces. For example, on March 17, 2007, three chlorine filled trucks were bombed in the Anbar province, killing 2 and sickening over 350 people. Other chlorine bombs caused the deaths of more than 30 people. The force of the explosions was worse than the toxic gases since the chlorine was burned or was dispersed in the atmosphere by the blast. Chlorine which is essential for providing safe drinking water for the population, is often transported in truck or train tankers and has become a sought after terrorist target. [http://www.webelements.com/webelements/scholar/elements/chlorine/history.html/][http://www.nytimes.com/2007/02/21/world/middleeast/21cnd-baghdad.html?partner=rssnyt&emc=rss]

The chloride ion is formed when the element chlorine picks up one electron to form an anion (negatively-charged ion) Cl−. The salts of hydrochloric acid [[HCl]] dissociate to contain chloride ions which can also be called chlorides. Another example is table salt, which is sodium chloride with the chemical formula [[NaCl]]. In water, it dissolves into Na+ and Cl− ions. The word chloride can also refer to a chemical compound in which one or more chlorine atoms are covalently bonded in the molecule. This means that chlorides can be either in [[inorganic]] or [[organic compounds]].[http://en.wikipedia.org/wiki/Chloride]